Hi J,
First let me caution you that most slates are usually considered a poor choice for exterior. Most of them will accept water into the body, freeze up, expand out, & blow the stuff apart. They do make several porcelain look-alikes that are extremely durable outdoors though.
You want to do your leveling before you do the crack isolation. Check our liberry for tips on using self leveling underlayment. Don't forget the primer for all jobs, & to abrade the surface if it's ever had sealers or coatings on it. For outdoor use, I would recommend a sheet membrane instead of a roll-on for crack isolation. Noble CIS or Nobledeck are great for this.
www.noblecompany.com