Hi Julie,
Wow, those planters look so good!
Great idea to bond the grout on the rims with tile mortar.
I use this cleaner often:
For something like your application, I'd have mixed about 3 oz (0.2 lbs) into a gallon of water and scrubbed it with white nylon pad.
To treat the grout you can't go wrong with this product:
http://www.drytreat.com/sealers/residential/40sk.html
That will repel water. Sealing it up entirely with a marine varnish or similar will alter the look and may lead to efflorescence again.