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You've strayed from the common realm of ceramic tile into the less common realm of Gauged Porcelain Tile Panels. The industry came out with a new standard in 2017 for such material and installation methods titled ANSI A137.3/108.19. You should probably see if you can gain access to that publication if you can.
For sure, you should ensure that your proposed installation contractor has a copy and that he can show you where it says his proposed method complies with the published material.
I've never installed those (usta be called Thin Porcelain Tiles) materials, but we (TYW) did attend some industry sponsored training in their handling and installation. While it is certainly similar to ceramic tile installation, there are some pretty dramatic differences and you want your contractor to be aware of those and, hopefully, equipped and experienced in their installation.
That said, I've not heard of his proposed method of installation and would be a bit skeptical of it.
As for your concrete slab condition, we'd need at least some photos and/or very specific descriptions to help with an assessment. The first question I'd have is whether one side of any of the cracks is higher than the other side. And that's even a few thousandths of an inch higher. You can sometimes compensate for cracks that are exactly in-plane from side to side, but not those with a height difference.
That includes your concerns "about using some sort of uncoupling." While there are Uncoupling membranes in the industry, there is no standard for them, and you're at the mercy of the manufacturer's advertising department as to their capabilities. On the other hand, there are standards for Crack Isolation Membranes (ANSI A118.12) that might be of more benefit to your installation. Operative word there is might. With those very large panels, it's difficult (impossible?) to shift the crack location in the tile surface.
There is also the consideration for flatness of your concrete substrate. Has your proposed contractor evaluated that on your behalf?
My opinion; worth price charged.