Sorry you've gotten overlooked, Mark.
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If you put a few drops of water on back, the front immediately turns dark, so I assume it is non vitreous. I had planned on using it on a bathroom floor and in a shower surround. Is that advisable?
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No.
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I know I will be greeted with more of the same if I inquire about tile types, so is there going to be a code or other marking on the box that will identify the tile type?
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Some times yes, other times, no. If you stick with the more visible tile companies, you can find out everything you need to know from the box, the website, or their tech support service. Lesser known tiles may be a crapshoot. If you have a box of the tile handy, scan or photograph it and we'll try to find answers for you.
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I just can't decide whether to caulk or grout the corners. If I grout the corners do I use a spacer?
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Caulk. Leave a 1/8" gap for the caulk. Spacers optional.
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The directions call for a roofing nail or drywall screw to be attached just above the flange with the edge catching the flange.
Is this going to put a lump under the backerboard when I hang it?
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Probably, but you can take a utility knife and remove some material from the back of the backerboard.
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How wide should this caulk line be? Should it be the same width where the wall tiles will meet the shower door frame?
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1/8" to 1/4". I think yoru caulk lines should be of consistant width, but that's just me. If it needs to be bigger for some reason, make it so. Just make it neat and workmanlike.
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But I still am wondering if I should prime the board first?
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If it can take paint, it can take thinset. No need to prime.