Art,
Keep your voice down. I'm gonna have the Tile Ranger on me again.
ANSI (Tile Council of America) standard suggest that all "changes of plane" be caulked, not grouted at all. But I'm a mud man, and I've been grouting everything for years. I don't intend to change. If, however, grout won't stay put, the only thing left is caulking.
Routinely caulking over grout is a really bad idea in my opinion. The very thin layer of caulk doesn't keep moisture out, but it keeps it in. The moinsture can't evaporate and you get the black looking mold behind the caulking. You can't wash it off because the caulking is in the way.
So one or the other. Wanna go by the book, use caulking. Wanna chance being sanctioned by the tile police, do it my way.