A porcelain tile is very nearly impervious, and so is the Ditra, so covering the area won't make much of a difference in the overall bond strength in this situation.
I've found that just spreading a coat of thinset on the back of porcelain may not actually do much unless it is done just so. You need to use a fair amount of pressure to get it embedded into the pores, and, if done right, the only way to get it off is to scrub it off (assuming it's not cured!), otherwise, it sort of tends to actually ball up a little if you get what I mean, and not really stick well.
There are a couple of types of modified that will work on both Kerdi and Ditra, but, the USA ANSI spec does not differentiate that characteristic, so Schluter was unwilling to let modifieds used, since, if they contained latex, they had problems, or at least could. But, there are 3 other classes of modifiers that can be used in thinset that could work...it's just that you can't tell by the ANSI spec (the European spec does differentiate). An unmodified, installed properly over Ditra or Kerdi does work, as will certain modifieds. One reason why Schluter came out with their own is to ensure people had an easy choice of one they know will work. That makes it a bit easier when you're dealing with a tile, such as glass, where the manufacturer insists you use a modified. FWIW, they've set glass tile for centuries before modified thinsets became available...done right, it works.
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Jim DeBruycker
Not a pro, multiple Schluter Workshops (Schluterville and 2013 and 2014 at Schluter Headquarters), Mapei Training 2014, Laticrete Workshop 2014, Custom Building Products Workshop 2015, and Longtime Forum Participant.
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